Explanation:
Because the solution only contains Na+ and Cl− ions, and water, and not the metal Na(s) . You cannot evaporate the water from the solution and hope to obtain anything but NaCl(s) .
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Na(s) has an electron configuration of 1s^2 2s^2 2p^6 3s^1 , but Na+(aq) has an electron configuration of 1s^2 2s^2 2p^6 . That means they are not the same element, and thus, there is no straightforward way of extracting Na(s) from a NaCl (aq) solution
